Racemic Mixture, Enantiomeric Excess and Walden Inversion | Isomerism Part 11 | JEE · NEET
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Racemic Mixture, Enantiomeric Excess and Walden Inversion | Isomerism Part 11 | JEE · NEET
39 просмотров · 2 недели назад
Layrd
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39 просмотров · 2 недели назад
A reaction flips the sign of rotation. Did the configuration change? Not necessarily.
📘 In this part (11 of 14)
1️⃣ Racemic mixtures and racemisation
2️⃣ Retention, inversion and enantiomeric excess
3️⃣ Resolution, asymmetric synthesis and Walden inversion
🧭 Topics in this video
• Racemic mixture and racemisation
• Retention, inversion and racemisation in reactions
• Enantiomeric excess and optical purity
• Resolution of racemic mixtures
• Asymmetric synthesis
• Walden inversion
✏️ Your turn: [α]obs = +6.75°, pure (+)-2-butanol = +13.5°. % of (+) form? Answer in the comments!
📄 Companion page, formula sheet and practice set: https://layrd.live
📚 Isomerism: all 14 parts (playlist: Isomerism | JEE · NEET | layrd.live)
• Part 1: Isomers: Chain, Position and Ring-Chain • Isomerism Basics: Chain, Position and Ring...
• Part 2: Functional Isomerism • Functional Isomerism: Every Family You Nee...
• Part 3: Metamerism • Metamerism: Ethers, Ketones, Amines, Amide...
• Part 4: Tautomerism and Keto-Enol Equilibrium • Keto-Enol Tautomerism: Enol Content, Mecha...
• Part 5: Other Types of Tautomerism • Other Tautomerism: Nitro, Oxime, Enamine, ...
• Part 6: Degree of Unsaturation and Counting Isomers • Degree of Unsaturation and Counting Isomer...
• Part 7: Geometrical (cis-trans) Isomerism • Geometrical Isomerism: Cis-Trans, Syn-Anti...
• Part 8: Optical Activity, Symmetry and Chirality • Optical Activity, Chirality and Chiral Cen...
• Part 9: Optical Isomerism Without a Chiral Carbon • Chiral Without a Chiral Carbon: Allenes, S...
• Part 10: Lactic Acid, Tartaric Acid and Counting Stereoisomers • Lactic Acid, Tartaric Acid and Counting Op...
▶ Part 11: Racemic Mixtures, Optical Purity and Configuration (this video)
• Part 12: Diastereomers, Fischer Projections and D/L Configuration • Fischer Projections, Diastereomers and D/L...
• Part 13: Conformations of Ethane, Propane and Butane • Conformations of Ethane and Butane: Newman...
• Part 14: Conformations of Cyclohexane • Cyclohexane Chair, Boat, Axial and Equator...
⏱ Chapters
0:00 Mixtures and reactions
0:16 Racemic mixtures and racemisation
0:53 Retention, inversion, racemisation
1:40 Enantiomeric excess and optical purity
2:49 Resolving a racemic mixture
3:46 Asymmetric synthesis
4:16 Walden inversion
4:51 JEE question + traps
5:33 Recap
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