Rate Determining Step and Mechanisms | JEE 2027 Chemistry (English)
RankDeterminant
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Rate Determining Step and Mechanisms | JEE 2027 Chemistry (English)
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RankDeterminant
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All lessons of this unit: • JEE 2027 Chemistry | Unit 8 Chemical Kinetics
How to get the rate law from a reaction mechanism for JEE Main and Advanced: order equals molecularity for an elementary step, the slow step as the rate-determining step, the fast pre-equilibrium method (k_obs = k2 K, Ea,obs = Ea2 + delta H1), the steady-state approximation, intermediates versus catalysts, peaks and valleys on an energy profile, and two solved problems, including ozone's negative order.
Chapters
0:00 Introduction
0:31 Elementary steps: order equals molecularity
1:31 Slow step first: the rate-determining step
2:30 Fast pre-equilibrium, then the slow step
3:53 Steady state: the intermediate stays nearly constant
4:35 Energy profiles, and the big trap
5:26 Example 1: rate law of 2NO2 + F2, F atom as intermediate
6:38 Example 2: ozone pre-equilibrium, order minus 1 in O2
7:58 Quick revision: slow step, pre-equilibrium, energy profile
A free JEE paper every day and a full JEE Main mock every Sunday: https://rankdeterminant.com/go/yt-dai...
Chemistry · Unit 8 · Chemical Kinetics · Chapter 5 · Mechanisms, Complex Reactions and Catalysis
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Narrated with a computer voice.