Reaction of Metal Carbonyl | Organomettalic Chemistry | CSIR NET DEC 2026 | Lec-7 | IFAS
Chemistry - CSIR NET, GATE & SET: IFAS
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Reaction of Metal Carbonyl | Organomettalic Chemistry | CSIR NET DEC 2026 | Lec-7 | IFAS
2 607 просмотров · Трансляция закончилась 2 нед. назад
Chemistry - CSIR NET, GATE & SET: IFAS
357 тыс. подписчиков
2 607 просмотров · Трансляция закончилась 2 нед. назад
Reaction of Metal Carbonyl | Organomettalic Chemistry | CSIR NET DEC 2026 | Lec-7 | IFAS explained with clear concepts and exam-focused approach. This session covers metal carbonyl reactions, CO stretching frequency trends, and ligand donor-acceptor effects. Master high-yield PYQs on bonding, acid strength, and thermal decomposition for CSIR NET success.
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⏳ Lecture Timeline:
[00:00:00] – Introduction: Reaction of Metal Carbonyl
[00:04:47] – Concept: Stretching Frequency & Bond Order
[00:05:29] – Example: CO+ vs CO Frequency
[00:07:14] – Comparing Cr, Fe, Ni Carbonyls
[00:08:56] – Role of Electronegativity
[00:10:54] – Ligand Types: Sigma vs Pi
[00:15:07] – Back Bonding & Frequency Order
[00:19:13] – Question 1: Ligand Donor Strength
[00:24:27] – Question 2: Cr(CO)5L Comparison
[00:27:31] – Question 3: Oxidative Addition Reaction
[00:30:51] – Example: CO, CO+, and Metal Charge
[00:33:52] – Acidity of Metal Carbonyl Hydrides
[00:35:10] – Question 4: HMn(CO)5 vs HRe(CO)5
[00:46:07] – Question 5: Acidity Order in Carbonyls
[00:52:52] – Concept: Steric Crowding Effect
[00:54:55] – Ligand Effects on Acidity
[00:57:26] – Important: Fe(CO)5 Thermal Reactions
[01:06:09] – Complete Session: (Reaction of Metal Carbonyl )
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📖 Topics Covered in This Lecture:
• CO Stretching Frequency: Bond Order & Back Bonding Concepts
• Ligand Effects: Sigma Donor, Pi Donor & Pi Acceptor Tricks
• Metal Carbonyl Hydrides: Acidic Strength Order Problems
• Influence of Metal: Electronegativity & Orbital Size on CO Stretch
• Thermal Reactions: Fe(CO)5 to Fe2(CO)9 to Fe3(CO)12
• Vaskas Complex & Oxidative Addition: IR Frequency Shifts
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📚 Lecture Summary:
In this session, IFAS Expert Faculty focuses on high-weightage Reaction of Metal Carbonyl problems for CSIR NET 2026. Key concepts include CO stretching frequency trends based on bond order, metal nature, and ligand type. Tricks for comparing acidic strengths of metal carbonyl hydrides and solving IR-based questions are discussed. This Reaction of Metal Carbonyl lecture builds a strong foundation for Organometallic Chemistry exam questions.
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🎓 This lecture is highly beneficial for students preparing for:
✅ CSIR NET Chemical Science ✅ GATE Chemistry ✅ SET Chemistry
✅ TIFR Chemistry ✅ BARC / DRDO / ISRO Exams ✅ PhD Entrance Exams
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