Fajans' Rules and Covalent Character | JEE 2027 Chemistry (English)
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Fajans' Rules and Covalent Character | JEE 2027 Chemistry (English)
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RankDeterminant
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This chapter: • The Octet Rule and Ionic Bonding | JEE Che...
All lessons of this unit: • Chemical Bonding & Molecular Structure | J...
Fajans' rules explained: how a small, highly charged cation polarises an anion and gives an ionic bond some covalent character, polarising power and polarisability, why a pseudo-noble-gas d10 cation such as Cu+ polarises more, the effects on melting point, solubility, colour and hydrolysis, and two JEE-style solved problems on NaCl, MgCl2, AlCl3 and on CuCl.
Chapters
0:00 Introduction
0:46 Polarisation: the cation pulls the anion's cloud
1:45 Rule 1: a small, highly charged cation
2:45 Rule 2: a large, highly charged anion
3:29 Rule 3: the cation's shell matters
4:31 More covalent character means...
5:19 Example 1: covalent character of NaCl, MgCl2, AlCl3
6:43 Example 2: why CuCl is more covalent than NaCl
8:10 Quick revision: small cation, large anion, d10 cation
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Chemistry · Unit 3 · Chemical Bonding & Molecular Structure · Chapter 1 · The Octet Rule and Ionic Bonding
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Narrated with a computer voice.