F BLOCK ELEMENT | One Shot Revision | MH SET | CG SET | JK SET | K SET | Lec 18 | IFAS
Chemistry - CSIR NET, GATE & SET: IFAS
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F BLOCK ELEMENT | One Shot Revision | MH SET | CG SET | JK SET | K SET | Lec 18 | IFAS
3 512 просмотров · Трансляция закончилась 1 мес. назад
Chemistry - CSIR NET, GATE & SET: IFAS
358 тыс. подписчиков
3 512 просмотров · Трансляция закончилась 1 мес. назад
F-Block Elements in Inorganic Chemistry explained with clear concepts and exam-focused approach. Learn Lanthanide Contraction, Magnetic Moment Deviations, Coordination Numbers, Ionization Energy Trends & PYQ solving for CSIR NET, GATE & SET.
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⏳ Lecture Timeline:
[00:00] – Introduction
[01:07] – Session Overview: F-Block Elements for SET Exams
[03:23] – Question 1: Lanthanide Complex Bonding & Coordination Number
[06:58] – Important: Coordination Number →8 (Ceric Nitrate = 12)
[07:37] – Question 2: Magnetic Moment & Spin-Orbit Coupling
[08:52] – Question 3: Zr–Hf Size Similarity (Lanthanide Contraction)
[10:05] – Question 4: Large Deviation from Spin-Only Formula (Samarium)
[11:36] – Question 5: Highest 3rd Ionization Energy (Eu, Yb)
[14:23] – Question 6: Partition Coefficient & TBP Solvent Extraction
[17:17] – Question 7: Solubility & Acidity/Basicity of Lanthanide Hydroxides
[19:14] – Question 8: Observed vs Calculated Magnetic Moment (Gd, Lu)
[20:32] – Question 9: Magnetic Moment Formula & Spin-Only Value
[22:15] – Question 10: Term Symbol & Unpaired Electrons (Sm³⁺, Eu³⁺)
[24:25] – Question 11: Reducing Character – Sm²⁺ vs Eu²⁺
[27:15] – Question 12: UO₂⁺ Disproportionation & U₃O₈ Stability
[29:35] – Important: Uranyl Complex Coordination Number = 8, Linear
[30:03] – Question 13: Uranium & Thorium Ores (Pitchblende, Monazite)
[32:25] – Question 14: Ceric Ammonium Nitrate – Diamagnetic (Ce⁴⁺, 4f⁰)
[33:27] – Question 15: Lanthanide Oxides Basic Nature & Sm²⁺ Stability
[35:46] – Question 16: Magic Numbers (2, 8, 20, 28, 50, 82, 126)
[38:46] – Question 17: Ceric Ammonium Nitrate as Oxidizing Agent & Colors
[40:34] – Question 18: Coordination Number of GdCl₃·6H₂O = 8
[42:47] – Question 19: Magnetic Moment Deviation – Sm vs Eu
[44:08] – Homework Question
[44:38] – End Of Lecture
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📖 Topics Covered in This Lecture:
F-Block Elements, Lanthanide Contraction, Magnetic Moment Deviations, Coordination Numbers, Ionization Energy Trends, Partition Coefficient, TBP Solvent Extraction, Magic Numbers, Ceric Ammonium Nitrate, Uranium Ores, Lanthanide Oxides Basicity
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📚 Lecture Summary:
In this session, IFAS Expert Faculty focuses on F-Block Elements for CSIR NET, GATE & SET. Key concepts include lanthanide/actinide bonding, lanthanide contraction, spin-orbit coupling and magnetic moment deviations (Sm, Eu), coordination numbers (Ce nitrate = 12), 3rd ionization energy trends (Eu, Yb), partition coefficient, TBP extraction, magic numbers, ceric ammonium nitrate, uranium ores, and PYQ-style problem solving.
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🎓 This lecture is highly beneficial for students preparing for:
✅ CSIR NET Chemical Science ✅ GATE Chemistry ✅ SET Chemistry
✅ TIFR Chemistry ✅ BARC / DRDO / ISRO Exams ✅ PhD Entrance Exams
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